Probably the best and easiest way is to fill a bucket with aquarium water, take the rock out that he lives in (if you know what rock it is), put it in the bucket and use a syringe with RO to flush him out. You will be very surprised how hard they are to catch otherwise.. If that is not appropriate, you can go the the hardware and get one of the live mouse trap catchers, and you can bait these.
Oh, if you do catch him, don't kill him.. he is only doing what he does in nature and it wasn't his choice to become a member of your tank. I am sure lots of people would be willing to take him.. I would but I'm not close.. you can keep him in the sump or a small perforated container stuck to the side until someone picks him up.
Best of luck.