Sure, there's chemistry involved. However, the only chemistry occurring is some addition of very weak acid in the form of H2CO3 from dissolved CO2 and some dilution. That's it with RO water. Keep in mind that this weak acid does not really affect alkalinity to any appreciable degree, but will depress pH. But basically, nothing happens with the addition of pure water, minus a drop in salinity (which is the effect of dilution) or a very insignificant drop in pH (we're talking tiny here). Basically, the reason it doesn't affect the chemistry so much is because there isn't really anything in it that would affect chemistry. So, no, there is no need to buffer your top off--buffering your top off could actually cause some calcium-alkalinity balance issues.