I don't know what type of calcium reactor you have so the exact description might be a little different. I have a Corallife reactor. The pH electrode fits in the top cap of the reactor with the rubber gasket. The plug-end of the electrode plugs into the middle connector at the bottom of the controller.
The power supply for the controller plugs into the left connector at the bottom of the controller.
The cable coming out of the right side of the bottom of the controller (permanently attached) should be connected to a large rectangular box with a plug on one side and an outlet on the other. Plug this box into an outlet.
Assuming you're using the controller to turn on and off the CO2 to the reactor, you will have a solenoid valve that connects to the outlet of the CO2 valve. Plug the power cord for the solenoid valve into the outlet on the black box that you plugged in in the previous step.