In a 75L tank (~20 USG) you could do a variety of small tropical fish. The best question is not what fish I would recommend. The best question is what type of fish do you like, and then research to see what sorts of living conditions they require. If you can provide it for them, congratulations, you've found a fish to keep.
I suggest you start
here. That is the link to the Species Profile section of Aquaria Central and it has fish and lists what tank size they need. You will want nothing listed over 20 gallons for a 75 litre tank.
If you are asking me what I would put into my own 20 gallon, I can answer that easily, as I have been researching and getting ready to set one up. I want a 20 gallon long, planted with low light plants, no CO2 injection, an RFUGF and a small sponge filter. In it I will place two trios of Endler's Livebearer's, a couple of Coryadoras Catfish, two otocinculus catfish and then let the Endler's get busy. I like Endler's because they are small, ultra-colorful and easy to breed. There is some speculation that they may also be extinct in the wild now as well, so I'd like a shot at keeping the gene pool more broken up by at least getting my own group going and then trading with other Endler's keepers down the road to see what we can do for these little guys.
So you see, it's best to do some research and find out what you wish to do on your own. If you have questions, you can always ask here on the boards about compatability. Most important rule of all is have fun and enjoy what you are doing. You will be happier and you will keep your fish happier, and really, I think that is what this board is all about.