Its a good thing if the person your getting the tank from has a for sale sign in front of their house. Thats the best reason for selling a tank. You should always question why they are selling their tank. You might also ask if they had neons if you plan to keep them. You don't want a tank that has had neon disease.
Next, check to make sure if everything works. The heaters and filters should turn on when plugged in. If the tank is up, then there is nothing to worry about. It should be obvious if it works.
Before you setup the tank, test it first especially if it was empty at the place you got it from. There could be new leaks or leaks they didn't tell you about. The garage or outside is a good place to test it.
It might not be such a good idea to use a tank that was used for saltwater if you want freshwater fish either. It will take some work getting all the salt off.
Some people sell the tank and the fish. I prefer to buy the tank and stand only because its a long shot that someone has the tank, fish, filter, etc. that I want. You can expect to get some decorations and gravel usually in the deal too. It all depends though. One guy gave me about a years worth of fish food with the tank I got from him plus a bunch of extras. Some people will throw in a lot of extras that aren't advertised.
Besides the tank, look at the stand. If the stand is wood, make sure it isn't rotted anywhere.