Just in case you didnt already know this, you need to start with an empty dry tank to do what you are talking about. I imagine it would be **** near impossible to try that with water/gravel in the tank already. Also, I would think it would be best to buy a single large piece of styrofoam and "carve" the rockface into it, then apply your cement mixture. Also, a good idea would be to allow this cement to cure on wax paper, to prevent it from cementing to the floor. Just some ideas, and I hope your background turns out great.
Oh, one more thing, you can mix sand with your concrete to give the "rock" extra texture.