I currently have a 10G as a breeding tank, a 20G high for a grow out tank for the smaller (newer frys) and a 50G tote for a grow out tank for the larger frys until they are ready to be traded in for store credit.
What are peoples general feelings about this fish (experience/temperament/activity/personality)?
I really like their personality. They are fun to watch as they are protecting their frys, mostly when I remove the cover that prevents them to see the smaller frys in the 20G high grow out tank. As an individual (in my community tank), the lone female hides when I come near the tank, but always fun to see her when she does decide stay out of the cave. She currently shares her territory with a yoyo loach (kribensis inside the cave, while the yoyo loach is guarding the entrance

) They would hide, if there weren't any other fishes in with them.
Is it suitable for a community tank with smaller fish (i.e. tetras, specifically neons)?
A breeding pair might be too aggressive for tetras, some of the larger faster tetras might work (like the Black Skirt Tetras and the Serpae Tetras). I've had Black Skirts and Serpae in with the breeding pair, but they started to rip the fins of the two species of fishes, so I had to take them back... for Tiger barbs. For the first spawn, they didn't attack the barbs that much, but for the second one, the female chased them around and around (the male just for a bit, but they were able to get away). A lone cichlid would do great. The first kribensis in the community tank (which is now the male of the breeding pair) was only aggresive towards the livebearers (strangely), while the female that's in the community tank right now is only aggressive towards the siamese algae eater (due to the colouring, must be), the yoyo loach (for trying to enter the cave) and in rare occasions, the otocinclus catfishes.
Will it fare alright in more acidic water (mid to low sixes)?
They would prefer to have a slightly acidic environment, but I've had them in alkaline envirnment and they have already spawned twice and I'm still waiting for another spawn (the female is hiding again, after I removed the second set of frys, she was just stuck in the cave, as she dug out the inside and placed the gravel at the entrance). The water parameters are at a pH of 7.4, GH of 150 ppm, kH of 80 ppm, temp at 80F and cycled with a nitrate level of 20 ppm. They are currently in with Apple Snails (I think, Golden Mystery Snails).
Are they plant friendly?
My breeding pair eats the roots of the vallisneria in with them, while the lone female doesn't eat any plants. It might depend on the individual fish, though. The frys, on the other hand, eat the Elodeas that I currently have with them.
Of course, this is just my experience with them. They are really fun to watch when kept as individuals or as a breeding pair.