soft rocks are much more likely to affect your pH as opposed to inert rocks like granite.
for example, limestone is often used a a buffer in many tanks with alk. needs, like cichlids.
off the top of my head...
most softer rocks will dissolve chemicals (could be good or bad, but why risk it...) into your water
and by soft, try taking somethign like a piece of quartz and scratching the surface of the rock in question. if the quartz scratches the rock, the rock has a hardness of less than 7 on the harness scale NOT TO BE CONFUSED WITH pH OR ALKALINITY IN ANY WAY
on the flipside, for all buffering purposes, it would be best to add some limestone to your tank, but please dont use crushed coral (yes, it affects FW too)
Good luck!
B.W.