discuspaul.. it has been in a few discussions.. most folks don't do proper maint on their hot water tanks. as a result sediment builds in the bottom.. also hotwater is more prone to leaching minerals from pipes and sediment.
I've seen it measure different using tds meters.. hot almost always higher TDS compared to cold.
as a result while I don't do cold water changes (I have done it with no ill effect btw) I tend to use a lot less hot water to temper the water.. now the water is cool.. but not matched.. I often think we forget that in nature water can fluctuate in temperature quite a lot with no ill effect on the fish .. but I don't mean freezing water to warm water .. just cooler water ...