Either is generally good...with the black substrate though I would say black background would likely be best. Will be very dramatic and your fish will really pop out. Try getting some coloured paper, put it behind the tank and see what your prefer. edit : with the black you probably want plenty greenery in there or it may look a bit too sombre, unless it is a rift lake cichlid tank in which case the colours of the fish are all you need
In fact I make my backgrounds out of mounting boards cut to fit and propped behind the tank - very easy to change them if you want.