You are correct that most fish can survive a wide range of pH, 6-8 (maybe 8.5) for most of the common ones, and controlling the Ammonia level is MUCH more important than pH.
But Clown Loaches, Discus and Ram Ciclids will not be very happy with a pH over 8. Likewise African Lake Cichlids will not be very happy at pH 6.
It becomes even more important if you expect the fish to breed, and then you may need to take some notice of the pH.
But the original question was about White Clouds and pH of 7.8, and thats perfectly OK, they will be happy, probably even breed.
The 9gal tank isn't an issue, it's big enough for White Clouds, and has nothing to do with the pH.
Ian