Petrified wood i THINK is primarily calcium carbonate (also known as limestone, marble, coral, chalk, hard water stains, etc). Created when water disolves limestone and is then filtered through wood buried in sediment. as the hardened water replaces that in the rotting vegetation the calcium carbonate crystalizes back into a solid form basicly using the original cell walls as molds. .... or something to that effect.
Assuming what i said is more or less correct. It will affect ph/gh/kh of the water but only if the water is under a certain ph. I think its 7.6. If ph is less greater than that the stone will not dissolve.
Of course if i am completely wrong then maybe someone else will clarify.
Breaking it... most sedementary rocks do not have cleavage (get your minds out of gutter). This means it will not break easily in nice smooth surfaces. On the other hand, since the individual chunks of limestone that crystalized follow the orderly nature of the original wood, It might break smoothly.
You could check some stone sculpturing (marble?) techniques online somewhere to find out how to make the rock break the way you want it.
Assuming everybody isn't still thinking of female pet rocks, I think I will close this encyclopaedia entry

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