I've just had a quick look, with a flashlight, up under the bottom of the only tank I have that's on an open metal stand. As RTR predicts, what's settled to the very bottom and is visible is the finest-textured pale ochre cat-litter silt, speckled with small dark brown bacterial colonies that could be sources of some hydrogen sulfide, which in turn must attract the sulfide-oxidizing bacteria that turn it to sulfate, since all souces of energy attract the bacteria that utilize them-- certainly in undisturbed freshwater microenvironments.
By the time organic particles have broken up and been broken down and have settled deep into low-oxic levels of the substrate, they have been so thoroughly stripped of their nutrients and so thoroughly reworked by detritivores and decomposers, that what remains isn't potentially harmful, just an excellent silty substrate for attracting iron or phosphate. And for anaerobic bacteria.
But if I were disturbing my substrates, all kinds of rich organic goodies would be finding their way down to anoxic levels, there to cause troubles with anaerobic decay.
(I'm completely ignorant of fish-only tanks: even my childhood guppies had Cabomba and Elodea to pick through. So I'm only describing the one kind of fishkeeping I know.)
By the time organic particles have broken up and been broken down and have settled deep into low-oxic levels of the substrate, they have been so thoroughly stripped of their nutrients and so thoroughly reworked by detritivores and decomposers, that what remains isn't potentially harmful, just an excellent silty substrate for attracting iron or phosphate. And for anaerobic bacteria.
But if I were disturbing my substrates, all kinds of rich organic goodies would be finding their way down to anoxic levels, there to cause troubles with anaerobic decay.
(I'm completely ignorant of fish-only tanks: even my childhood guppies had Cabomba and Elodea to pick through. So I'm only describing the one kind of fishkeeping I know.)