dont believe any fish advise from an instruction book that has 3 gold fish in a biorb lol
It really depends on how much water change you want to do, biorb itself has a very good filtration system. Currently i have 6 zebra danio and 4 whiteclouds, and water change once a week is more than enough. My nitrate never reachs over 15ppm. (40ppm is considered the threshold). I plan to add a guppy and platie to that mix as well.
So you can definitly add some more fish if doing weekly water change, just make sure the max length is 2" or less. On the other hand if you want to just do a monthly water change like the book said, then i advise against any more fish.
Btw i would not recommend putting a catfish in biorb, I assume it's a panda cory or something similar when you say small cat fish?
The bottom media rocks are very sharp, and definitly not suited for a bottomfeeder fish. They will eventually cut themselves and die, and those cory are schooling fish so having just 1 is also bad. I put cherry red shrimps as the bottom dweller, they are very cool to look at and eats algae and leftover food. You may want to consider that instead of bottomfeeder fish.
gaga
ps: all this is based on your birob is already cycled -> ammonia 0, nitrite 0. search cycling on this forum if you not sure what that is.