Guppygal's problem is that her tank is too acidic, not too basic (the initial pH in her tank was below the pKa). This means she won't produce carbonate with baking soda, but sodium chloride and CO2.
Of course, you are right and the soda buffers the system, and its pKa is spot on. But the specific question was how long soda will stabilize the system, and my answer was: Not too long, if you don't add secondary, non-volatile buffers, keep the soda in solution by CO2 injection, or both. This would also prevent pH swings. Adding soda to a non-buffered acidic system will immediately rise the pH considerably.
Of course, you are right and the soda buffers the system, and its pKa is spot on. But the specific question was how long soda will stabilize the system, and my answer was: Not too long, if you don't add secondary, non-volatile buffers, keep the soda in solution by CO2 injection, or both. This would also prevent pH swings. Adding soda to a non-buffered acidic system will immediately rise the pH considerably.