Tom - so no PO4 level for plants, but how about maximum PO4 levels for fish?
There is no standard for PO4 toxicity for fish, it's used like most any salt, and can be toxic based on the salinity, rather than say acute toxicity like with Copper which cross links disulfide bridges and oxidizes various enzymes and membranes.
PO4 got a bad name from algae blooms where no plants are present.
If you have plants growing in moderately to high abundance, adding PO4 = more plants.
The weed growth or algae bloom, can have indirect effects on fish by reducing, eliminating O2, particularly if they all start dying off and release large amoutn sof decompsoed plant or algae matter into the water. That is consumed by bacteria, which suck out all the O2.
Lack of O2 is what causes the fish kills typically.
A few species of algae release chemicals that can kill fish etc, but no plants do this.
pH buffers are often made from PO4 based products that target less than 7.0pH. pH down is H3PO4 (30%)for example, or it use to be. Salts of PO4 are used for a number of uses.
Soaps no longer uses it make it sud up however due to water quality concerns.
NO3 is also fairly non toxic, but if you load the same NH4, it's extremely toxic, so if you start with dosing KNO3, that is very different than loading with fish waste and NH4(typically the case with aquarist/fish only advice).
I've yet to have met anyone that's killed any fish/shrimp with KH2PO4 and KNO3.
Folks kill fish and shrimp all the time, at least weekly on the forums (mis)using CO2 gas. But few give that a bad name like PO4/NO3.
Never understood that one.
Regards,
Tom barr