I'd also advise against rainwater. Despite there being no industrial areas in your immediate area, there are many pollutants that can be transported hundreds and even thousands of miles in the atmosphere before falling to ground when it rains.
An extreme example that is easy enough to visualize would be whenever a volcano has a serious eruption and the distance traveled by the volcanic dust / ash. Think of the Mt. St. Helens eruption in 1980. Volcanic ash traveled from Washington state all the way into the Midwestern US. And, that's simply the distance traveled by particulate ash that settled out on its own in many places without the aid of any rainfall. The distance that a water soluble chemical could travel before falling with the rain could be significantly further, depending on the amount of moisture in the atmosphere, atmospheric wind speeds, and the amount / frequency of rainfall.
Or, think of it in terms of how people with moderate to severe allergies might. Rainfall "cleans" a lot of dust and other allergens out of the air. Any collected rainwater is likely to contain any number of various dust types, depending on the dust sources impacting the area where you live. The compounds that make up that dust could be problematic for a tank. Even if there's only dissolved organic matter in the rainwater (from local trees, other plants, and birds), it could be a sizeable source of ammonia as it breaks down... ammonia that you wouldn't want to put into your tank.
Ultimately, there's just too many variables to trust unfiltered, unprocessed rainwater for a saltwater tank. If there's any plans to keep inverts or corals, there's even less room for error, making the use of unfiltered, unprocessed rain water any even riskier gamble.