I'm still searching for the perfect thing to use to build a rockscape for the loaches.
Right now I'm using rocks. They work well, but they're a little hard to customize.
I was going to build a base out of foam and then cover that with a coat of concrete, possibly reinforced with a modeling mesh. I'd been looking at quick-curing concrete and at grout, liking its texture and wide color assortments. Except that concrete is made with lime, and lime will tend to drive up the pH. And I don't want to do that.
I was thinking that a good coat of epoxy or some other type of waterproofing might help mitigate this, but I haven't found anything conclusive on that. Haven't run any trials yet, still researching a few other avenues. The epoxy and plaster route could work, just seems like it'd easy to have it go wrong. Some area neclected or damaged could start to undermine it. If you really want to go that route I'd run a few trials first.
Other folks have done backs with foam, either styro or the expanding stuff, and sprinkled sand on a few successive epoxy coats. Works.
I also was reading something the other day that gypsum (plaster) would drive up your GH and make your tank look like chowder, but not effect KH.