You need to make sure your kH is 3.0°H.....MINIMUM before injecting the tank with CO2. If you don't know your water's kH, test it or get it tested.
Raising kH is what increases your buffer and protects your fish from a pH crash.
For their saftey, don't inject until you know your kH.
If you have a pH of 6.5 without injecting, my guess is that you may well need to increase kH.
Just from the sounds of it, you've got soft water.
Len