Gold girl, welcome to AC!
The reason your fish are suffering is from nitrite and ammonia poisoning, as Somervell suggested. Your 50 gallon tank is not cycled. By "cycled" we are talking about the process of growing a bacteria colony in the filter that will process ammonia and nitrite, both highly toxic chemicals from fish waste, into nitrate. A cycled tank will not show any ammonia or nitrite levels because the bacteria colony will feed on them and turn them into nitrate, a less toxic chemical.
While a tank is cycling, the levels of ammonia and nitrite will spike viciously, which can make your fish sick and cause the convulsions you mentioned. Since you have far too many fish in the 50 gallon tank, the fish are producing very high levels of ammonia and nitrite, without an established bacteria colony to process those chemicals.
You will need to read our thread on cycling a new tank, which can be found here:
http://www.aquariacentral.com/forums/showthread.php?t=84598
Rather than "treating" the tank - I'm not sure what you mean by that - you will need to do a large water change immediately with dechlorinated water. A good dechlorinator like Prime or AmQuel will remove the chlorine and chloramine from your tap water to make it safe for fish.
You should also remove the "cleaner fish" and the catfish from the tank. Goldfish should never be kept with catfish. As soon as the catfish is large enough to fit a goldfish in its mouth, it will! Any fish advertised as a "cleaner fish" certainly is not. Plecos and cories are both sold as such, but require specialized tank conditions and food of their own. Neither are compatible with goldfish.
You mentioned you are new to goldfish. A quick primer: The first thing you need to know is that pond goldfish (the single-tailed variety) can grow up to 18 inches long and the smallest tank they should be kept in is a 60 gallon. They are omnivorous fish and should be fed a quality sinking pelleted food, supplemented with fresh vegetables like romaine lettuce and parsley. Goldfish have no stomach and due to their large size, can produce a large amount of waste, so they need a filter rated for about twice the tank size. For example, a 60 gallon tank would need a filter rated for a 120 gallon. They are also highly intelligent and will learn to recognize their owner and can be trained to eat from your hand. Goldfish can live 15-30 years, the record being 43 years.
Feel free to ask any questions you may have. We're here to help! Best of luck with your goldies.