I don't think guppies would keep to the top very much. They're sort of midlevel...if you are keeping it cool for them (high 60s, low 70s) then you might try some bloodfin tetras or danios of some sort, pearls are the prettiest IMO of the common pet store variety but I know there are much nicer ones such as D. choprai or D. roseus.
Oh and by the way, love your tank! Adorable little cats
Oh and by the way, love your tank! Adorable little cats