Depending on the shape of the available peices of obsidian, it may or may not blend into the substrate, which could be cool or not depending on the structure(s, if any) you build with it. Let me make a couple of suggestions about that, then: 1) Obsidian is glass. Be very careful to dull all edges with a file, particularly if you break any of it into smaller pieces (if you have or can lay hands on a dremel, that would make it really light work.) 2) it might look really cool to take a could 2 or 3 large sized pieces and lay them sort of randomly on/in the substrate. 3) if you have some small pieces (thumb sized to two or three times that) tie some anubias to them and tuck them in your driftwood or any rockwork you build. 3) Using a combination of rounder and flatter pieces, you could build a honeycomb rock pile for the left side of the tank that would make a great hiding place for you bichir, Ctenos if you get them, or any cichlids or catfish you get. You can distribute the weight by sinking a piece of egg crate lighting diffuser in the gravel under where you'r'e putting the pile (file the corners on that too, if you have any diggers), and you can reduce the weight by builing an interior structure out of PVC tubing (so the rockwork would be a shell to cover up the PVC cave system.) Soften the whole thing with Anubias and/or Java Moss and/or Bolbitis.
Have you considered maybe putting a tiger lotus or two in there?