You indeed have salvinia minima and duckweed both, the salvinia is the larger of the two.
The top browning pic looks like it was caused by physical damage, the second one is normal for the leaf, color veining, if it looks and feels like the leaf is getting thinner then its a problem, if its still solid then its normal.
An increase in light would help on the 75 and DIY co2 on it is futile. It would take a ton of 2 liter bottles to make it even feasible to work. Look into pressurized.
Iron is not a normal deficiency, I wouldnt worry about dosing it just yet. Work on the light situation.
Your 30 gallon has sufficient light for low to medium low light plants.