Okay, the tannins in some wood can/will effect the results when comparing kH/pH for CO2 ppm. I use drift and bog wood in all my tanks and according to my ppm results, all my fish should have been dead years ago. I have experimented with pushing the envelop just a tad at a time to determine when the fish are affected and so I now know what "ppm" is safe for my fish.
Example: my kH is a steady 3.5 and my pH reads a steady 6.3. The chart tells me that that yields a CO2ppm of approx. 50-55.
This figure is made inaccurate due to the tannins in the wood. I have found that the amount or the inaccuracy is dependent on the amount of wood in the tank. In a 10 gal. tank, it wouldn't take much wood to affect your results.
This, of course is much easier to do with pressurized CO2 that remains stable, than with DIY, but it can be done with DIY if you are observant and careful with bottle changes.
Len