Anybody know what this is?

It's beneficial bacteria. That in your tank will help keep your ammonia down.

If that was true, that would be the biggest bacteria in this universe.
 
Detritus or mulm. Folks should regularly lift their rocks/decorations, if possible, and gravel vacuum underneath them. If you have a big array of rocks, then using a powerhead or other water jet to flush the detritus out from under and between the rocks and then doing your gravel vacuum and tank maintenance would also work.
 
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