If you just wish to raise you KH, you're probably better off just adding a smidge of baking soda or tossing some cleaned seashells/sand in the filter media bay.
However, if you are doing this for your plants, ie... vallisneria... the stuff I use is about $4 for a 50lb bag at Home Depot. SouthDown Playsand is the name, think it still has a red or blue label on the bag. It's composed of oolitic aragonite sand and has a fairly narrow range of particle sizes, from fine to dust. The same stuff that many of the marine aquarists use in their DSBs.
I'll either use it alone in a tank where I don't mind a pH in the upper 7's, or mix it in with a thin layer of peatmoss (for CEC) and cover it with Onyx or whatever substrate I'm using in my planted tanks. Even when it composes about 1/2 of my overall substrate, I don't see any notable pH rises (tap water is about 7.2-7.4) once the substrate has matured for about 2-3 months and the tank has had weekly 50% water changes. During the first month or two, you may note the pH raising to around 7.6-7.8 (in my experience, with my well water) between water changes. After all the fine particles are either filtered out and the substrate settles, the pH will be less prone to fluctuate. Note: If your tap water is in the 6.x pH range, you may notice a greater effect than I have. My pH settles in at around 7.4. Now how much the hardness is raised... I am uncertain. However, KH tests I believe are an acid precipitation test which is actually testing alkalinity... ?
Ideally, add about 3-4 cups sand and 1 cup peatmoss for every 18 square inches or so to the bottom of a new setup, then cover with your preferred substrate. Just make sure the peatmoss is spread nice and thin and evenly, you won't want to create an anoxic environment. Feel free to use more sand if you like, personally I like the appearance and find it holds down roots pretty well while still permitting easy uprooting.