1) Lower pH is bad for marine fish
2) Urea is acidic
3) build up of urea causes lower pH
4) addition of buffers will correct lower pH - UP TO A POINT
5) once you've added a certain amount of buffer, the negative components of the buffer mixture will lower pH despite the addition of additional buffer.
This is basic chemistry. There is nothing that can increase the pH of marine water once certain chemical pathways are saturated.
yup. with freshwater, its the same.
its the bicarbonate buffer system. its the chemistry of H20, CO2, and CaCO3 and the associated equilbriums.