Silicone does NOT absorb copper. A simple rinse, and if you want, little bleach if it makes you feel better, and the tank will be perfectly fine. I dare anyone to show me any real proof that copper used in a tank in the past and then given even a simple rinse poses any threat to anything in the future. Glass and silicone do not absorb stuff. I can show you my 29G reef tank that has been dosed with copper many times and still flourishes today and the only thing I ever did was put it in the bathtub and fill up with water, let overflow for about a minute, drained, and reused.
Sorry, but that is one "Myth" about copper that is told so many times without any proof and it is one of my pet peeves.