I have six small pieces of mopani wood from Petco (between two tanks), and I love them. They will probably turn the water brown for at least two weeks, with regular water changes, but personally, I like the effect. 
Sometimes they'll throw in a random piece of wood that isn't mopani, though - I found a piece that wasn't mopani, and I haven't had any troubles with it, but it did flake off a few small, loose pieces of wood during the first couple of weeks. Just be careful that it's not some stick off the street.
If you want caves/tunnels, just keep an eye out for bent pieces! A lot of times you'll find some that already have unique shapes, twists, and holes that make tunnels and hidey-holes naturally. I don't think you should have any trouble if you want to take a drill to the wood (never done it myself), but there are a lot of cool shapes out there which require less effort.
The piece on the far right of this picture is an example of what you can find
The middle piece has a branch that makes an arc, too (more recent picture in my signature's "10 gallon" link). My fish love swimming through it.

Sometimes they'll throw in a random piece of wood that isn't mopani, though - I found a piece that wasn't mopani, and I haven't had any troubles with it, but it did flake off a few small, loose pieces of wood during the first couple of weeks. Just be careful that it's not some stick off the street.
If you want caves/tunnels, just keep an eye out for bent pieces! A lot of times you'll find some that already have unique shapes, twists, and holes that make tunnels and hidey-holes naturally. I don't think you should have any trouble if you want to take a drill to the wood (never done it myself), but there are a lot of cool shapes out there which require less effort.
The piece on the far right of this picture is an example of what you can find
