Sorry, I didn't mean to imply that plants will absorb toxins. I don't use carbon with them (probably same reason as you) because the carbon will absorb some of the metals they need as nutrients. But I have been told on this forum that plants can act like a filter and keep your tank in cleaner condition. I assume it's because they "eat" ammonia and nitrate as food. I don't think they can actually remove toxins/poisons. If you have specific concerns, maybe you should post a threat in the Aquatic Plants section. People there are pretty knowlegeable.
In case of toxins, I would just stick in an activated carbon filter to remove most of them. Long-term, it will probably deprive your plants. But short-term, it's probably more important to get rid of whatever's harming your tank. I guess I would leave it in for a day or two, then dose for plant nutrients immediately after removing the chemical filter. Of course do water changes in conjunction with that, to remove the source of the problem.
This is what I do after routine water changes. I use carbon for a couple hours, just in case I had anything toxic on my arms (sunscreen, etc.) or in case the decorations got ahold of some soap or chemicals while in my sink. Of course, I wash my hands and sink beforehand, but just in case. After I take out the carbon, I dose my plants.