A 65 gallon tank would make an ideal setup for a good number of goldfish, say 2 or 3 large bodied types or even 3 to 4 of the smaller fancies. As a rule, goldfish are very sociable creatures and do better for many reasons with their own kind than with non-goldfish tankmates. That being the case, there are so many different kinds of goldfish and the variety in body size, color, shape, and finnage is quite amazing. So this isn't as restrictive as it may seem at first.
For suitable tankmates other than goldfish... yes, that's very limited due to the unique requirements goldfish have, either in swimming space/water volume, diet, water temp, size, or temperament. But you do have some choices available that are sure bets you can count on not to lead to problems of one kind or another. Those are weather loaches (dojos), apple snails (briggs/diffusas and the like), and white cloud mountain minnows (depending on goldfish type in terms of size).
While many other native species fish from cold water lakes/streams prefer the same cold water temperature range, these need protein-rich foods which, of course, would also be eaten by the goldfish. Goldfish are true gluttons whenever any food is available to them. Too many proteins can lead to digestive problems for the goldies (who require a much more varied diet) and unduly high tank maintenance requirements for the fishkeeper (as excessive proteins passing through undigested would then break down and decay in the water column).
As mentioned already, Plecos would not make a good choice. They are tropical fish who need warmer temperatures and who pose an ever-present risk to goldies due to their natural attraction to sucking on the protective goldfish slime coat and the obvious physical damage that would result. Plecos are also unable to tolerate most medications needed for treatment should the goldfish develop signs of infection, disease, or parasites.