Any form of carbonate will raise the buffering, a.k.a. alkalinity or carbonate hardness (KH). Sodium bicarbonate (baking soda) is highly soluble so works in a flash. Go easy with it. Calcium carbonate is the stuff of shells and coral. The "crushed coral"substrate used in marine tanks is calcium carbonate. It dissolves slowly. Buy a cheap cupful from the open bag at the lfs.
Increase the alkalinity/buffer/KH and your pH will rise. If you don't want higher pH, you don't want additional alkalinity.