You will need to look at the hitchhikers on the live rock to determine if you have copper poisoning. Specifically, look to see if you get any sponges, worms, crabs, feather dusters, anemones, etc. If you see any of these creatures begin to look bad or sick or something like that, then I would start testing for copper. I think that I have heard someone here say that Salifert makes a reliable copper test.
Also, it can't hurt to put in a snail (I'd try Astrea) and see how it fares. Sanils are very sensitive to copper levels, so that ought to be a very good test of whether or not your substrate leeched any copper.