Google Henry's Law for an explanation.
When co2 outgasses, it does not mean it forms an equilibrium with the amount of co2 concentrated in the atmosphere. Water naturally only holds around 3-4ppm of co2 depending on pH and hardness. It's the same law that causes sodas to go flat. Unless co2 is added faster than it is outgassed, water's natural co2 constant will eventually return to 3-4ppm.
When co2 outgasses, it does not mean it forms an equilibrium with the amount of co2 concentrated in the atmosphere. Water naturally only holds around 3-4ppm of co2 depending on pH and hardness. It's the same law that causes sodas to go flat. Unless co2 is added faster than it is outgassed, water's natural co2 constant will eventually return to 3-4ppm.