I am by no means an expert on the subject, but to the best of my knowledge, in order to determine what nm a given bulb peaks in you have to see the spectral graph of that bulb. If you cannot find it, then the color temp (kelvin)
will give a good idea as to where the bulb peaks. Low Kelvin 3000K or so will have more red, high Kelvin 10,000K more blue. Daylight bulbs 5000K-7500K have the full spectrum with a lot of green. Which is what the human eye sees as brightness. So to achieve the 2/3 red, 1/3 blue & appeal to my eye, what I done was use two bulbs that peak in the red (aqua-glo I believe) & two Daylight 6700K bulbs.
It really was overwhelming to me at first, because I'm somewhat of a perfectionist. But I've come to terms with the fact that I cannot duplicate nature & my plants are growing so I'm happy for now.