Dan the Fish said:your F-stop should be 60 at least or i believe its ISO on a digital.
To avoid confusion, i'll clear up the mixing of three different terms here.
F-stop refers to aperture. You want the lowest possible aperture for the widest opening. If you have a zoom lens, zoom all the way out because your widest apertures aren't going to be available at higher zoom.
The 60 he's referring to is a 1/60 of a second shutter speed. That's a good place to start for hand holding. Any slower than that and you'll probably want to rest the camera on something or get a tripod.
ISO is completely different still. It's the light sensitivity of your film or imaging sensor. Higher numbers mean more sensitive, but you'll get a grainier picture. For fish photography, you're in very low light, so go with the highest ISO you can get. For film, get a good quality 800-speed film. For digital, go with the highest your camera will support.
If you have ways of getting more light over the tank temporarily, go for it. If you can get more light, your first step is to use a faster shutter. Then if you have a fast enough shutter, give yourself a lower ISO for a better photo. Leave your aperture wide open. That'll narrow your focus to the fish itself, throwing the fore- and background out of focus.