Unfortunately, a direct comparison between RO/DI units would really need to be done over time. Any single reading from the units would likely provide similar results, but over time, a measurable difference is more likely. In the same regard, if the two units are not being supplied by the same source water, the comparison isn't quite as useful.
When it's said that the more expensive units are better, it's been my understanding that it's something that is seen over time... RO membrane longevity, frequency of DI resin replacement... What tends to be better (other than individual part / fitting quality) is the reduced long term operating costs of the more expensive RO/DI units.