Both produce water devoid of its ionic content, but by different means. I doubt it means much to the fish.
Actually, most reverse osmosis membranes are fairly inefficient at reducing many common (and small) ions. That is why deionization resins are needed if you want to reduce ion content to lower levels. Certain ions, like H2S, silicate, phosphate, and CO2 aren't entirely removed and may not be removed satisfactorily for at least some applications. Granted, small, uncharged molecules can and will pass quite freely through the entire unit, regardless of the inclusion of DI resins. Keep in mind that this applies to TDS as well, since the real TDS is at least a little higher than what you are measuring.