I would recommend baking soda to raise the KH of the water, but baking soda is a base. It will raise the KH though. What you might be able to do is run some peat moss in the tank. I'm not very sure about peat moss, for I have high PH fish and therefore can't experiment with it.
Raising the KH is counter-productive for lowering the ph, as the OP stated his original intent is. Raising the alkalinity will buffer the ph up, not down and will offset the addition of peat or other acidifiers.
OP - I would follow RBishop and Mg's advice and learn more about your source water and its parameters before monkeying with the water chemistry.
Mark