no i do 25% water 1/3 gravel, nitrates are food waste, fish waste etc etc, when i gravel vac i do 1/3 each time twice a week which is roughly 66 % of my substrate weekly, nitrates are in the substrate/filter not the actual water right? , theres no logical reason why my nitrates are still 60 i have been doing things for 2 years to get it down and theres nothing that has worked i have even done 3 PWC a week even a 4th which actually killed off some fish cause i was over cleaning and killed my bio bed cause i was also doing the filters every week as well, i feed small 2 x a day for 4 days which i dont like doing so i am actually thinking of going back up to 5, you rremove nitrates by gravel vaccing and cleaning filters and if you have decor where food can get trapped in it or am i totally confused?