I'm under the impression that with vodka dosing and other types of carbon dosing the nitrate and phosphate is processed by different types of bacteria not associated with the typical denitrification process.
Supposedly this/these bacteria do not require oxygen-free environments to process nitrate (which is the case with the denitrification via deep sand beds, live rock etc which can provide anaerobic zones).
Supposedly this/these bacteria do not require oxygen-free environments to process nitrate (which is the case with the denitrification via deep sand beds, live rock etc which can provide anaerobic zones).