... We need to have the anaerobic area, and having small, golf ball sized live rock rubble chunks in the sump WILL provide this for us.
... The minimum size of live rock capable of sustaining denitrifying anoxic bacteria would depend on the porosity of the rock, but is very rarely smaller than a large fist size.
OK, we seem to disagree on the smallest size rubble to use

what's important is that we both agree that there is a minimum size limit...
Although even small pieces of rock would have *some* anoxic areas, it stands to reason that larger rocks (of the same density/porosity) would have larger anoxic interiors, thus having larger "substrate" for the growth of more nitrate reducing bacteria. Of course, on the bottom of a very slow moving area of the tank/sump the O2 level in the water surrounding the rubble would become anoxic as well, and the whole golfball size rock would become anoxic, but then one would not have much aerobic filtration in that piece of rubble.
Many years ago I experimented with adding an anoxic region filled with plastic hair curlers (cheap equivalent to bio balls...) below a wet/dry trickle filter, and this worked quite well in reducing nitrate. I later replaced the curlers with ceramic filter "noodles" called BioMax (distributed by Hagen) and this worked even better, keeping the nitrate level below 20ppm, even though each "noodle" was only slightly larger than a thumb nail. I later removed the trickle filter, increased the amount of large pieces of live rock, and added a deep live sand bed, and within a short period the nitrate level dropped to less than 1ppm.
Given the above, I still maintain that fist-size rock (or larger...) gives a better "balance" of aerobic and anoxic bacteria, thus allowing for OPTIMAL filtration - oh, and it does not matter if you have it in the tank or sump.
Just to clarify a final point: I'm not saying that small LR rubble is bad, only that it is not a very efficient nitrate reducing filter. Small pieces of LR rubble in the tank or sump provide the ideal breeding ground for many small critters who will assist overall filtration by eating detritus, and as an added bonus become food for your corals and fish, so by all means do add some rubble to your sump :grinyes: