Are the 2 o.k fish physically bigger than your sick pair? In my first batch, i bought 5 tiger barbs and the 4 largest bullied the smaller barb, he was left with no food, no shelter and they eventually killed him in much the same manner as you've described (swimming near the surface, hanging round the filter, etc.), i've now got 9 and they are very happy chappies! Its hard because you want to follow the advice of books and forums and only introduce a small number of fish at first, but tiger barbs maybe the one exception. Just make sure the tank is well and truely cycled before hand and a larger number could be introduced to start off (7-8 possibly). I wish i'd followed this route to start with.