well i'm not too familiar with the geology of the pacific northwest. the barnacle shells will be harmless as long as they are empty.
to check for calcium content you can drip a couple of drops of vinegar on the rock - if it fizzes then it has calcium.
you could try soaking it in a bucket of water for a week or so. if you see the rock change in color (i.e. rust) or in shape and texture it might mean its breaking down. if it stays the same and the water remains fairly clear, most likely it won't cause a problem.
if you still have doubt, keeping a good supply of carbon and being ready for a few quick water changes is a good safety blanket.
another option would be to look up a local geology professor at a community college and ask him his opinion.
sorry i can't be of more help