I don't think that the issue here is likely to be overdose as much as imbalance. Excess of one mineral ion out of "normal' proportion to another can give "deficiency" symptoms in the plants, likely due to uptake/transport competition or inhibition.
This is something I had considered as a possible issue. I don't have much of an understanding at all of nutrient competition, I always worked from the premise that there was one limiting factor, and if other needs were in excess it would not matter. Is it possible that the lack of one thing essentially blocks the plants ability to use another?
I don't have Ca/Mg issues as my water is moderately hard (GH ~9, or ~160ppm as CaCO3)
One of the thngs that led me to the idea of Tampering with GH was the hardness numbers I have seen you post elsewhere. My numbers (Unless I have grossly mis-understood my test kit) are much higher than yours after my additions. I do run very high light very high nutrient tanks, so there is some difference but I wouldn't think that much. When I switched from coral to aragonite I saw a rapid increase in GH and started backing down my dosing. As soon as I backed things down the plants went downhill.
The following has all taken place over the course of the last 16 months or so. one step at a time.
I first started dosing Mg Based on reccomendations from John, there was some improvement but I also began seeing more prominent symptoms of calcium defeciency. I then started upping my Ca, both through dosing of CaCL and through crushed coral in the substrate. I saw improvement with the calcium additions. I switched to Aragonite instead of or in addition to crushed coral primarily for more stability for shrimp and snails. The plants did O.K, but I still did not have the growth that I wanted, and could not even come close to the growth that John was getting. I then started searching for other missing links. I Purchased some of Tom Barr's GH booster from Gregg Watson, and read the ingredients. Manganese happened to be one of them so I checked with the local water company and they report 0 manganese in our water. since I don't use enriched substrates in most of my tanks, and Tom Barr felt manganeese was important enough to put in his GH booster I explored that. Light manganeese dosing did help as well. Iron is also removed from our tap water, and since I don't use enriched substrates, I dose heavy iron (have from the beggining) I am fearful of too much iron becaue of my shrimp and snails but honestly do not know how much is too much. I dose my traces via CSM+B+Fe from Gregg watson. one would think that would provide enough iron for my plants needs.
John uses eco-complete which contains manganeese and iron both but his tank now has enough age on it that I would think there is some limit to the benefit from the substrate.
I'll do an iron test today and see what I come up with. I've had a kit for a while but have been re-assured several times that testing wasn't needed and I probably had plenty of Fe.
Aside from Fe, Ca, Mg, and Mn what elements would be critical to plant balance. The trace mix is supposed to cover virtually everything else as I understand it.
Just an FYI, our water company uses alum to remove all metals. I don't fully understand the process but according to the tech I spoke to It essentially captures most if not all earth metals and removes them. They do this to produce water with 0 lead and 0 iron. Ca and Mg remain in trace quantities, but all other metals are gone. In the 9 years I've lived here I have never once seen an iron stain on anything that gets wet. Evaporated water barely leaves a spot on anything.
dave