What's the rule for rocks?

If you ever worried about whether the rocks that you have are chemically safe, its always an idea to quarantine them in their own bucket for a few days then test the water parameters. Althought thats not neccessary most of the time. Im led to believe most hard rock is fine as long as its cleaned and boiled.
 
Rose quartz, amethyst, or any kind of quartz would look rather fake in an aquarium.

Depends on what look you are going for.
 
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