Since it was mentioned, Any of the play sands or calcium carbonate based sands will do just fine as a substrate. For one, the argonite sand (calcium carbonate) is not going to buffer your tank. For cal.carb. to dissolve and buffer your tank, it would take an acidic pH of your water to do so. Which might happen deep down in an undisturbed sandbed, but no where near enough to where you could measure an actual benefit. Think about it, if calcium carbonate could dissolve (buffer) the tanks above sand water, then your stony corals would be in big trouble, as would the wild reefs. (they already are though due to CO2, but thats another topic). Oh, and silicate based sand is not going to dissolve and add silicates to your water either, such sands are in a form that are not soluable, just like the glass our tanks are made of. I still wouldn't recommend silicate sands anyways, but only because the grains are shaped very sharply and do not provide a good environment for sand dwelling critters.
Chuck