Does having the CO2 off at night rise the ph by morning? Or does it take a lot more time for that reaction to happen?
Yes, the pH should rise. Maybe 1 full unit.
It also rises if you do say a 50-80% water change inside a few minutes, and yet fish and plants are fine, week after week after week, years after year,.........
But........a good effective CO2 diffusion method will knock the pH back down in 30-45 minutes, or add 30-40ppm in this same time frame.
If you cannot get it down this fast, then you need a better CO2 diffuser and better mixing, flow through the system.
pH does not matter much here.
Co2 does.
Also, pH change is not bad/problematic, since it's not due to salts, TDS, KH etc......CO2 is not a dissolved solid nor a salt. KH/baking soda is, so if you changed the pH 1 full unit using baking soda, you better believe this will cause issues. CO2 is very different.
Most advice on pH does not factor this CO2 enrichment into things.
So the advice is not applicable to CO2 enrichment methods about pH.
Regards,
Tom Barr