The first question is whether or not your silica sand really is that. Make a cleaned sample of the sand (about 1/2 glass) with multiple RO rinses, then leave it is a glass bowl with its own volume again of RO, cover w/glass or waxed paper, and monitor daily for TDS. Much sand on the market is not pure silica. Southdown being one of the better examples. A good acid test (muriatic or such -dilute HCl, not table vinegar) is easier, but not quantitative.
Repeat for the lava rock - I had one batch which released heavy metals - I should have known better, it was quite dense stuff.
The percentage of dissoved CO2 present as carbonate/bicarbonte is quite small, I have it somewhere, but not handy. It is low enough that except well past biologically viable levels of CO2, I doubt that you would find it significantly detectable on TDS - detectable with good meters, yes, significant, doubtful.