Electricity in tank

Let me see if I understand this.

1. You measure a voltage between the tank and the ground on the power strip.
2. This voltage is present whether the grounding probe is plugged in or not.
3. The voltage goes away when you unplug the pump.

A couple of ideas.
1. It's not current leaking out of the pump, but the field generated by the coils of the pump that is causing a current and therefore a voltage drop between the tank and ground. It would have to be a big field, but it's possible.
2. If the pump is actually leaking, which would be really dangerous, then you should be able to measure a finite resistance between the tank and the pump's plug (unplugged of course). I am hoping that your voltmeter is a multimeter and can be used as an ohmmeter as well. Unplug the pump, put one lead of the ohmmeter in the tank, one on a prong from the pump (check all 3). It will give you a reading if there is contact between the pump and the water. It will not give you a reading (open circuit) if there is no contact.
3. What's going on with the ground lead? If it's functional, there should be only a small resistance between the two ends. So is it getting to ground? One thing that should work is plugging it into the same powerstrip as the pump, and checking the voltage again. A functional grounding probe will short out the voltage drop between the tank and the strip, and the meter should read 0 V.
4. The pump may actually be generating a stray voltage in the ground of the powerstrip. In effect, the voltage you're measuring is in the strip, not the tank. This is unlikely, assuming the contact between the powerstrip and house ground is good.
5. The third prong of your outlet is not really grounded. This does not exclude any of the other ideas, but would complicate your measurements of tank voltage, because you wouldn't be comparing the tank to ground, just a floating point.

As far as the whole chlorine thing, I am still baffled. If there is electrolysis generating chlorine and ultimately hypochlorite ion, then the volatge should be enough to ring your bells.

I hate to pass the buck, but I am not a chemist. This sounds like a question for Randy Holmes-Farley over at Reef Central. You might assemble all of the details you have presented here and ask him.
 
I still want to know how you came to the conclusion that the chlorine is coming from the electrical leak...

Where is your top off water coming from?
 
electricity

My top off water comes from an RO/DI water system. All I know is if I use a declorinator life in the tank lives if not they start to die. I just happen to check the water for current. I am puzzeled as to what is happening and why.
 
electricity

Maybe I explained it wrong. I put the positive lead of the ohm meter in the water, I put the groung lead of the ohm meter on the different prongs of the plug. The ohm meter didn't move on the positive or the common prongs of the plug. I did get a reading of .053 on the ground of the plug from the pump.
 
You have a circuit. I'm not sure how, but there is contact between the housing of the pump and the tank.

Here's an idea. It's the basis for how we used to coat our silver electrodes with silver chloride. We put a small voltage across an uninteresting electrode (we used graphite) and a silver wire, both dipped into a saturated NaCl solution. Chloride is deposited at one pole, chlorine gas is liberated at the other.

Could that be the source of your chlorine? Dunno. If I'm right, there have to be 2 "electrodes" in the tank. What is the other? The grounding probe? Another piece of equipment? The experiment is relatively simple. Check the connection between the tank and ground. Have you got a circuit? Then disconnect everything until there is no longer contact.

In the long run, you will be much safer with a new pump. I have a few other ideas about testing the hypothesis, but would feel really awful if you killed yourself.
 
Good luck. I feel like I am grasping at straws.
I would love to hear that it solved the problem, but it will at least make the tank safer for you (I hope).
 
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